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Distribution of polycyclic aromatic hydrocarbons in coke plant wastewater

Authors
Burmistrz Piotr  Burmistrz Michał        
Journal
Water Science and Technology
Year   Vol. Number Pages
2013  68  11   2414-2420
Impact Factor
1.212
DOI
Abstract in the main language of the article
Keywords in the main language
ścieki koksownicze  współczynnik podziału  wielopierścieniowe węglowodory aromatyczne (WWA)      
Title in the additional language
Abstract in the additional language
The subject of examinations presented in this paper is the distribution of polycyclic aromatic hydrocarbons (PAHs) between solid and liquid phases in samples of raw wastewater and wastewater after treatment. The content of 16 PAHs according to the US EPA was determined in the samples of coke plant wastewater from the Zdzieszowice Coke Plant, Poland. The samples contained raw wastewater, wastewater after physico-chemical treatment as well as after biological treatment. The ?PHA16 content varied between 255.050 ?g L(?1) and 311.907 ?g L(?1) in raw wastewater and between 0.940 and 4.465 ?g L(?1) in wastewater after full treatment. Investigation of the distribution of PAHs showed that 71-84% of these compounds is adsorbed on the surface of suspended solids and 16-29% is dissolved in water. Distribution of individual PAHs and ?PHA16 between solid phase and liquid phase was described with the use of statistically significant, linear equations. The calculated values of the partitioning coefficient Kp changed from 0.99 to 7.90 for naphthalene in samples containing mineral-organic suspension and acenaphthylene in samples with biological activated sludge, respectively.
Keywords in the additional language
coke plant wastewater  partitioning coefficient  polycyclic aromatic hydrocarbons (PAHs)      
 
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